Among the isotope systems exploited by mantle geochemists to deduce the chemical evolution of the Earth, those of the rare gases are unique because they record the migration of volatile species from the mantle to the atmosphere. The isotopic composition of helium in mantle-derived rocks is now reasonably well known, and it suggests that this migration has been both more heterogeneous and less extensive than commonly expected. The implications of the helium data are profound, but they seem to conflict with widely held beliefs derived from other geochemical tracers, including the isotopic characteristics of lithophile elements (that is, elements such as Sr, Nd, and Pb found predominantly in Earth's silicate rust). Although the geochemical pr...